In given Relationship of oxygen production to flash energy, the first evidence for the interaction between the antenna pigments and the reaction centre, What conclusion can be drawn about based on graph;

a.) several hundred pigments are associated with each reaction centre and that each reaction centre must operate four times to produce 1 molecule of oxygen—hence the value of 2500 chlorophylls per O2

b.) low light intensity of the curve, an increase in the number of photons stimulates a proportional increase in oxygen evolution. Thus, the slope of the curve measures the quantum yield for oxygen production

c.) The quantum yield for a particular process can range from 0 →if that process does not respond to light to 1.0→if every photon absorbed contributes to the process by forming a product

d.) O2 require more than a single photochemical event to be formed, and therefore have a lower quantum yield of formation than the photochemical quantum yield. It takes about ten photons to produce one molecule of O2, so the quantum yield of O2 production is about 0.1

Which of the following statements would be correct relates with graph?

#Question id: 403

#Unit 1. Structure and Function of Biomolecules

For the reaction A -> B, DG'° = –60 kJ/mol.  The reaction is started with 10 mmol of A; no B is initially present.  After 24 hours, analysis reveals the presence of 2 mmol of B, 8 mmol of A. Which is the most likely explanation?

#Question id: 404

#Unit 1. Structure and Function of Biomolecules

When a mixture of 3-phosphoglycerate and 2-phosphoglycerate is incubated at 25 °C with phosphoglycerate mutase until equilibrium is reached, the final mixture contains six times as much 2-phosphoglycerate as 3-phosphoglycerate.  Which one of the following statements is most nearly correct, when applied to the reaction as written?  (R = 8.315 J/mol·K; T = 298 K)  3-Phosphoglycerate -> 2-phosphoglycerate

#Question id: 405

#Unit 1. Structure and Function of Biomolecules

When a mixture of glucose 6-phosphate and fructose 6-phosphate is incubated with the enzyme phosphohexose isomerase (which catalyzes the interconversion of these two compounds) until equilibrium is reached, the final mixture contains twice as much glucose 6-phosphate as fructose 6-phosphate.  Which one of the following statements is best applied to this reaction outlined below? (R = 8.315 J/mol·K; T = 298 K) Glucose 6-phosphate -> fructose 6-phosphate

#Question id: 406

#Unit 1. Structure and Function of Biomolecules

Hydrolysis of 1 M glucose 6-phosphate catalyzed by glucose 6-phosphatase is 99% complete at equilibrium (i.e., only 1% of the substrate remains). Which of the following statements is most nearly correct? (R = 8.315 J/mol·K; T = 298 K)

#Question id: 407

#Unit 1. Structure and Function of Biomolecules

The reaction A + B -> C has a DG'° of –20 kJ/mol at 25° C.  Starting under standard conditions, one can predict that:

#Question id: 408

#Unit 1. Structure and Function of Biomolecules

Which of the following compounds has the largest negative value for the standard free-energy change (DG'°) upon hydrolysis?