TLS Online TPP Program

#Question id: 10631


To estimate the number of foxes m an area, a researcher conducted a mark-recapture survey. In the fast survey, he caught and marked 90 foxes. In his second survey a week later, he caught 120 foxes of which 40 were marked (recaptures). If you are told that the actual number of foxes in this area is 400, which of the following is a plausible explanation for the anomaly in the researcher's data? 

#Unit 10. Ecological Principles
  1. Capture increased mortality in the marked foxes
  2. Large mortality of foxes between the two surveys 
  3. The marked foxes were more likely to avoid recapture
  4. The marked foxes were more likely to be recaptured 
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TLS Online TPP Program

#Question id: 379

#Unit 1. Molecules and their Interaction Relevant to Biology

A compound has a pKa of 7.4. To 100 mL of a 1.0 M solution of this compound at pH 8.0 is added 30 mL of 1.0 M hydrochloric acid. The resulting solution is pH:

TLS Online TPP Program

#Question id: 380

#Unit 1. Molecules and their Interaction Relevant to Biology

The Henderson-Hasselbalch equation:

TLS Online TPP Program

#Question id: 381

#Unit 1. Molecules and their Interaction Relevant to Biology

Consider an acetate buffer, initially at the same pH as its pKa (4.76). When sodium hydroxide (NaOH) is mixed with this buffer, the:

TLS Online TPP Program

#Question id: 382

#Unit 1. Molecules and their Interaction Relevant to Biology

The molar ratio of sodium acetate to acetic acid in a buffer solution with a pH OF 5.76 is 10:1. Assuming the total buffer concentration is 2.2 X 10-2 mol/L, how many grams of sodium acetate (m.w. 82) and how many grams of acetic acid (m.w. 60) should be used in preparing a litre of the solution?

TLS Online TPP Program

#Question id: 383

#Unit 1. Molecules and their Interaction Relevant to Biology

Three buffers are made by combining a 1 M solution of acetic acid with a 1 M solution of sodium acetate in the ratios shown below

1 M acetic acid              

1 M sodium acetate  

Buffer 1: 10 mL

 90 mL

Buffer 2: 50 mL

50 mL

Buffer 3: 90 mL

10 mL

 Which of these statements is true of the resulting buffers?

TLS Online TPP Program

#Question id: 384

#Unit 1. Molecules and their Interaction Relevant to Biology

A solution was prepared by dissolving 0.02 moles of acetic acid (HOAc; pKa = 4.8) in water to give 1 liter of solution. What is the pH? To this solution was then added 0.008 moles of concentrated sodium hydroxide (NaOH). What is the new pH? (In this problem, you may ignore changes in volume due to the addition of NaOH).