A very common isotope substitution is when hydrogen is replaced by deuterium. This is known as a deuterium effect and is expressed by the ratio kH/kD (as explained above). Normal KIEs for the deuterium effect

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#Question id: 27065

#Section C (Domain-Specific Knowledge)

Determine R and S Configurations On A Fischer Projection given below 

TLS Online TPP Program

#Question id: 27066

#Section C (Domain-Specific Knowledge)

Determine R and S Configurations On A Fischer Projection given below 

TLS Online TPP Program

#Question id: 27067

#Section C (Domain-Specific Knowledge)

Choose the correct statement regarding the stereochemistry of amino acid

1. 16 amino acid except (Thr, Ile, Cys, Gly) L Fischer projection is equal to S and D is equal to R configuration 

2. Thr, Ile is special case because of two chiral center exist in L – Ile/Thr – 2S,3R and D-Ile/Thr–2R,3S configuration  

3. Cys exiest in L- Cys – R & D- Cys – S configuration 

4. Gly is optically inactive 

TLS Online TPP Program

#Question id: 27068

#Section C (Domain-Specific Knowledge)

Isoleucine and Threonine have two chiral carbons so exists in multiple RS configuration, choose the correct option regarding the given fig.

1. a is D-threonine is (2S, 3S) threonine

2. b is L-threonine is (2R,3S) threonine

3. a is L-threonine is (2S, 3R) threonine

4. b is D-threonine is (2R,3S) threonine

TLS Online TPP Program

#Question id: 27069

#Section C (Domain-Specific Knowledge)

Choose the correct option regarding the stereochemistry of given compound 

TLS Online TPP Program

#Question id: 27070

#Section C (Domain-Specific Knowledge)

Which of the following statements is correct regarding the stereochemistry of Thr, Ile 

1. Thr, Ile is special case because of two chiral center exist in L-Ile in 2R,3S and L-Thr in 2R,3S configuration 

2. Thr, Ile is special case because of two chiral center exist in D-Ile in 2R,3S and D-Thr in 2R,3S configuration 

3. Thr, Ile is special case because of two chiral center exist in L–Ile in 2S,3R and L–Thr in 2S,3R 

4. Thr, Ile is special case because of two chiral center exist in D–Ile in 2S,3R and D–Thr in 2S,3R