TLS Online TPP Program

#Question id: 3805


A newly replicated DNA duplex is likely to have:

#XL - Q Biochemistry
  1. nucleosomes both from the parental DNA and newly assembled.

  2. nucleosomes, each with histones both from the parental nucleosomes and newly synthesized.

  3. nucleosomes either all newly synthesized or all from the parental strand.

  4. a random combination of both nucleosomes and individual histones, both newly synthesized and from the parental strands.

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TLS Online TPP Program

#Question id: 447

#XL - S Microbiology

In glycolysis, fructose 1,6-bisphosphate is converted to two products with a standard free-energy change (DG'°) of 23.8 kJ/mol.  Under what conditions encountered in a normal cell will the free-energy change (DG) be negative, enabling the reaction to proceed spontaneously to the right?

TLS Online TPP Program

#Question id: 448

#XL - S Microbiology

During glycolysis, glucose 1-phosphate is converted to fructose 6-phosphate in two successive reactions: Glucose 1-phosphate -> glucose 6-phosphate DG'° = –7.1 kJ/mol Glucose 6-phosphate -> fructose 6-phosphate DG'° = +1.7 kJ/mol DG'° for the overall reaction is:

TLS Online TPP Program

#Question id: 449

#XL - S Microbiology

The standard free-energy changes for the reactions below are given. Phosphocreatine -> creatine + Pi DG'° = –43.0 kJ/mol ATP ->  ADP + Pi DG'° = –30.5 kJ/mol What is the overall DG'° for the following reaction? Phosphocreatine + ADP -> creatine + ATP

TLS Online TPP Program

#Question id: 450

#XL - S Microbiology

The DG'° values for the two reactions shown below are given.

Oxaloacetate + acetyl-CoA + H2O -> citrate + CoASH DG'° = –32.2 kJ/mol

Oxaloacetate + acetate    ->   citrate DG'° = –1.9 kJ/mol

What is the DG'° for the hydrolysis of acetyl-CoA?

Acetyl-CoA + H2O -> acetate + CoASH + H+

TLS Online TPP Program

#Question id: 459

#XL - S Microbiology

Calculate △G°ʹ for the reaction shown if the mass action ratio, Q, is 5.3 × 102 M-1 and △G is 46 kJ/mol at a temperature of 298 K. (R = 8.315 J/K-mol)

ADP + Pi ⇌ ATP

TLS Online TPP Program

#Question id: 462

#XL - S Microbiology

The formation of acetyl CoA is driven to completion by