TLS Online TPP Program

#Question id: 24166


The term spices is a pleasant one, whether it connotes fine French cuisine or a down-home, cinnamon-flavored apple pie. ____________. In the past, individuals traveled the world seeking exotic spices for profit and, in searching, have changed the course of history. Indeed, to gain control of lands harboring new spices, nations have actually gone to war.

#General Aptitude
  1. The taste and aroma of spices are the main elements that make food such a source of fascination and pleasure.
  2. The term might equally bring to mind Indian curry made thousands of miles away and those delicious barbecued ribs sold on the corner.
  3. It is exciting to find a good cookbook and experiment with spices from other lands—indeed, it is one way to travel around the globe!
  4. The history of spices, however, is another matter altogether, and at times, it can be filled with danger and intrigue.
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TLS Online TPP Program

#Question id: 381

#Unit 1. Molecules and their Interaction Relevant to Biology

Consider an acetate buffer, initially at the same pH as its pKa (4.76). When sodium hydroxide (NaOH) is mixed with this buffer, the:

TLS Online TPP Program

#Question id: 382

#Unit 1. Molecules and their Interaction Relevant to Biology

The molar ratio of sodium acetate to acetic acid in a buffer solution with a pH OF 5.76 is 10:1. Assuming the total buffer concentration is 2.2 X 10-2 mol/L, how many grams of sodium acetate (m.w. 82) and how many grams of acetic acid (m.w. 60) should be used in preparing a litre of the solution?

TLS Online TPP Program

#Question id: 383

#Unit 1. Molecules and their Interaction Relevant to Biology

Three buffers are made by combining a 1 M solution of acetic acid with a 1 M solution of sodium acetate in the ratios shown below

1 M acetic acid              

1 M sodium acetate  

Buffer 1: 10 mL

 90 mL

Buffer 2: 50 mL

50 mL

Buffer 3: 90 mL

10 mL

 Which of these statements is true of the resulting buffers?

TLS Online TPP Program

#Question id: 384

#Unit 1. Molecules and their Interaction Relevant to Biology

A solution was prepared by dissolving 0.02 moles of acetic acid (HOAc; pKa = 4.8) in water to give 1 liter of solution. What is the pH? To this solution was then added 0.008 moles of concentrated sodium hydroxide (NaOH). What is the new pH? (In this problem, you may ignore changes in volume due to the addition of NaOH).

TLS Online TPP Program

#Question id: 387

#Unit 1. Molecules and their Interaction Relevant to Biology

For a weak acid with a pKa of 6.0, What would be the ratio of acid to salt at pH 5.

TLS Online TPP Program

#Question id: 389

#Unit 1. Molecules and their Interaction Relevant to Biology

A weak acid HA has a pKa of 5.0.  If 1.0 mol of this acid and 0.1 mol of NaOH were dissolved in one liter of water, what would the final pH be?