TLS Online TPP Program

#Question id: 71


Which of the following is not the priority rule for R, S Configuration?

#Section C (Domain-Specific Knowledge)
  1. If the four atoms attached to the chiral center are all different, priority depends on atomic number, with the atom of lower atomic number getting lower priority.

  2. If the two atoms attached to chiral centers are same, the atoms attached to each of these first atoms are compared

  3. When there is a double bond or triple bond, both atoms are considered to be duplicated or triplicated

  4. If the four atoms attached to the chiral center are all different, priority depends on atomic number, with the atom of higher atomic number getting lower priority.

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TLS Online TPP Program

#Question id: 10189

#Section C (Domain-Specific Knowledge)

A very common isotope substitution is when hydrogen is replaced by deuterium. This is known as a deuterium effect and is expressed by the ratio kH/kD (as explained above). Normal KIEs for the deuterium effect

TLS Online TPP Program

#Question id: 10190

#Section C (Domain-Specific Knowledge)

Arrange the protium, deuterium and tritium water in increasing order of molarity. Suppose density 1g/ml.

TLS Online TPP Program

#Question id: 10191

#Section C (Domain-Specific Knowledge)

Statements are given as
A. Primary kinetic isotope effects are rate changes due to isotopic substitution at a site of bond breaking in the rate determining step of a reaction.
B. Solvent shows primary kinetic isotope effect
C. Secondary kinetic isotope effects are rate changes due to isotopic substitutions at a site other than the bond breaking site in the rate determining step of the reaction.
D. Solvent shows primary kinetic isotope effect and secondary kinetic effect as well
Which of the following is correct combination of statements

TLS Online TPP Program

#Question id: 10257

#Section C (Domain-Specific Knowledge)

Lattice energy is inversely proportional to sum of radii of

TLS Online TPP Program

#Question id: 10258

#Section C (Domain-Specific Knowledge)

Arrange in the decreasing order of Lattice Energy (kj/mol)

TLS Online TPP Program

#Question id: 10259

#Section C (Domain-Specific Knowledge)

Which molecule has the largest dipole moment?