TLS Online TPP Program

#Question id: 358


Consider the following reaction at equilibrium: CO2 + H2O ⇔ H2CO3. What would be the effect of adding additional H2O?

#Unit 1. Molecules and their Interaction Relevant to Biology
  1. It would drive the equilibrium dynamics to the right.

  2. It would drive the equilibrium dynamics to the left.

  3. Nothing would happen because the reactants and products are in equilibrium.

  4. Reactions in both the directions will slow down.

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TLS Online TPP Program

#Question id: 381

#Unit 1. Molecules and their Interaction Relevant to Biology

Consider an acetate buffer, initially at the same pH as its pKa (4.76). When sodium hydroxide (NaOH) is mixed with this buffer, the:

TLS Online TPP Program

#Question id: 382

#Unit 1. Molecules and their Interaction Relevant to Biology

The molar ratio of sodium acetate to acetic acid in a buffer solution with a pH OF 5.76 is 10:1. Assuming the total buffer concentration is 2.2 X 10-2 mol/L, how many grams of sodium acetate (m.w. 82) and how many grams of acetic acid (m.w. 60) should be used in preparing a litre of the solution?

TLS Online TPP Program

#Question id: 383

#Unit 1. Molecules and their Interaction Relevant to Biology

Three buffers are made by combining a 1 M solution of acetic acid with a 1 M solution of sodium acetate in the ratios shown below

1 M acetic acid              

1 M sodium acetate  

Buffer 1: 10 mL

 90 mL

Buffer 2: 50 mL

50 mL

Buffer 3: 90 mL

10 mL

 Which of these statements is true of the resulting buffers?

TLS Online TPP Program

#Question id: 384

#Unit 1. Molecules and their Interaction Relevant to Biology

A solution was prepared by dissolving 0.02 moles of acetic acid (HOAc; pKa = 4.8) in water to give 1 liter of solution. What is the pH? To this solution was then added 0.008 moles of concentrated sodium hydroxide (NaOH). What is the new pH? (In this problem, you may ignore changes in volume due to the addition of NaOH).

TLS Online TPP Program

#Question id: 387

#Unit 1. Molecules and their Interaction Relevant to Biology

For a weak acid with a pKa of 6.0, What would be the ratio of acid to salt at pH 5.

TLS Online TPP Program

#Question id: 389

#Unit 1. Molecules and their Interaction Relevant to Biology

A weak acid HA has a pKa of 5.0.  If 1.0 mol of this acid and 0.1 mol of NaOH were dissolved in one liter of water, what would the final pH be?