TLS Online TPP Program

#Question id: 407


The reaction A + B -> C has a DG'° of –20 kJ/mol at 25° C.  Starting under standard conditions, one can predict that:

#1. Molecules and their Interaction Relevant to Biology
  1. at equilibrium, the concentration of B will exceed the concentration of A.

  2. at equilibrium, the concentration of C will be less than the concentration of A.

  3. at equilibrium, the concentration of C will be much greater than the concentration of A or B.

  4. C will rapidly break down to A + B.

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TLS Online TPP Program

#Question id: 391

#1. Molecules and their Interaction Relevant to Biology

In a hospital laboratory, a 10.0 mL sample of gastric juice, obtained several hours after a meal, was titrated with 0.1 M NaOH to neutrality; 7.2 mL of NaOH was required. The patient’s stomach contained no ingested food or drink, thus assume that no buffers were present. What was the pH of the gastric juice?

TLS Online TPP Program

#Question id: 393

#1. Molecules and their Interaction Relevant to Biology

Carbon dioxide (CO2) is readily soluble in water, according to the equation CO2 + H2O ↔ H2CO3. Carbonic acid (H2CO3) is a weak acid. If CO2 is bubbled into a beaker containing pure, freshly distilled water, which of the following graphs correctly describes the results?

TLS Online TPP Program

#Question id: 400

#1. Molecules and their Interaction Relevant to Biology

Consider two solutions: solution X has a pH of 4; solution Y has a pH of 7. From this information, we can reasonably conclude that ________.

TLS Online TPP Program

#Question id: 401

#1. Molecules and their Interaction Relevant to Biology

.Which of the following graphs describes the relationship between [H3O+] and pH?

TLS Online TPP Program

#Question id: 402

#1. Molecules and their Interaction Relevant to Biology

If the DG'° of the reaction A -> B is –40 kJ/mol, under standard conditions the reaction:

TLS Online TPP Program

#Question id: 408

#1. Molecules and their Interaction Relevant to Biology

Which of the following compounds has the largest negative value for the standard free-energy change (DG'°) upon hydrolysis?