Nurturing Life Sciences
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#Id: 7845
#Unit 1. Molecules and their Interaction Relevant to Biology
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When the anomeric hydroxyl of a D-hexose is on the same side of the ring as C-6, the structure is β a by definition; when it is on the opposite side from C-6, the structure is α.
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The two diastereomers of glucose in its "pyranose" form are called the alpha (a) and beta (B) isomers, which differ in the orientation of the OH at C-1
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The pyranose form of glucose dominates (>99%) at equilibrium in aqueous solution
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The 6-membered cyclic form of sugars is usually called the “pyranose” form in reference to the cyclic ether pyran.
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The pyranose forms of the sugars are more stable than the furanose forms in solution.