TLS Online TPP Program

#Question id: 64


Testosterone and estradiol are male and female sex hormones, respectively, in many vertebrates. In what way(s) do these molecules differ from each other? Testosterone and estradiol ________.

#Section C (Domain-Specific Knowledge)
  1. are structural isomers but have the same molecular formula

  2. are cis-trans isomers but have the same molecular formula

  3. have different functional groups attached to the same carbon skeleton

  4. are enantiomers of the same organic molecule

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TLS Online TPP Program

#Question id: 68

#Section C (Domain-Specific Knowledge)

Match the following functional groups given in column I with their respective representatives given in column II.

COLUMN ICOLUMN II
1. Anhydridea. RCOOR
2. Etherb. ROCOCH3
3. Acetylc. ROR
4. Amidod. RCOOCOR
5. Estere. RCONH2

TLS Online TPP Program

#Question id: 69

#Section C (Domain-Specific Knowledge)

Which of the following is the diastereomer of the following compound?

TLS Online TPP Program

#Question id: 70

#Section C (Domain-Specific Knowledge)

The dimensions of living cells are limited, on the lower end by the minimum number of biomolecules necessary for function, and on the upper end by the rate of diffusion of solutes such as oxygen. Except for highly elongated cells, they usually have lengths and diameters in the range of

TLS Online TPP Program

#Question id: 71

#Section C (Domain-Specific Knowledge)

Which of the following is not the priority rule for R, S Configuration?

TLS Online TPP Program

#Question id: 72

#Section C (Domain-Specific Knowledge)

For the reaction catalyzed by the enzyme hexokinase: Glucose + ATP → glucose 6-phosphate + ADP the equilibrium constant, Keq, is 7.8 × 102. In living E. coli cells, [ATP] = 5 mM, [ADP] = 0.5 mM, [glucose] = 2 mM, and [glucose 6-phosphate] = 1 mM. Which of the following conclusions made on the basis of the above calculations is incorrect?

TLS Online TPP Program

#Question id: 73

#Section C (Domain-Specific Knowledge)

Match the Variation of Reaction Spontaneity (Sign of ΔG) given in Column I with the Signs of ΔH and ΔS given in column II.

COLUMN I

COLUMN II

 

 

 

  ΔH

ΔS

ΔG = ΔH – TΔS

1.

+

a. The reaction is both enthalpically and entropically opposed. It is nonspontaneous (endergonic) at all temperatures.

2.

 −

− 

b. The reaction is enthalpically opposed (endothermic) but entropically favored. It is spontaneous only at temperatures above T = ΔH/ΔS.

3.

+

+

c. The reaction is enthalpically favored but entropically opposed. It is spontaneous only at temperatures below T = ΔH/ΔS.

4.

+

d. The reaction is both enthalpically favored (exothermic) and entropically favored. It is spontaneous (exergonic) at all temperatures.