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TLS Online TPP Program

#Question id: 9157

At 15-30°N, air masses formed over the Pacific Ocean are moved by prevailing westerlies, where they encounter extensive north-south mountain ranges. Which statement best describes the outcome of this encounter between a landform and an air mass?

#SCPH28 | Zoology
  1. The cool, moist Pacific air heats as it rises, releasing its precipitation as it passes the tops of the mountains. This now warm and dry air cools as it descends on the leeward side of the range.
  2. The warm, moist Pacific air rises and cools, releasing precipitation as it moves up the windward side of the range. This now cool and dry air mass heats up as it descends on the leeward side of the range.

  3. The cool, dry Pacific air heats up and picks up moisture from evaporation of the snowcapped peaks of the mountain range, releasing this moisture as precipitation when the air cools while descending on the leeward side of the range.

  4. These air masses are blocked by the mountain ranges, producing high annual amounts of precipitation on the windward sides of these mountain ranges
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TLS Online TPP Program

#Question id: 15465

#SCPH05 I Biotechnology

50 g benzaldehyde vapour is condensed at 179°C. What is the enthalpy of the liquid relative to the vapour?  (Standard latent heat for vaporisation for benzaldehyde is 38.40 kJ gmol-1)
TLS Online TPP Program

#Question id: 15466

#SCPH05 I Biotechnology

Water at 25°C enters an open heating tank at a rate of 10 kg h-1. Liquid water leaves the tank at 88°C at a rate of 9 kg h-1; 1 kg h-1 water vapour is lost from the system through evaporation. At steady state, what is the rate of heat input to the system?
h (liquid water at 25°C = 104.8 kJ kg-1) 
h (liquid water at 88°C = 368.5 kJ kg-1) 
h (saturated steam at 88°C = 2656.9 kJ kg-1)
TLS Online TPP Program

#Question id: 15467

#SCPH05 I Biotechnology

Fumaric acid is produced from Malic acid using Fumarase. Calculate standard heat of reaction for the following transformation:
C4H6O5 → C4H4O4 + H2O
Given: (Δhc°)malic acid= -1328.8 kJ/gmol 
   (Δhc°)Fumaric acid= -1334.0 kJ/gmol
TLS Online TPP Program

#Question id: 15468

#SCPH05 I Biotechnology

In downstream processing of gluconic acid, concentrated fermentation broth containing 20% (w/w) gluconic acid is cooled in a heat exchanger prior to crystallisation. 2000 kg h-1 liquid leaving an evaporator at 90°C must be cooled to 6°C. Cooling is achieved by heat exchange with 2700 kg h-1 water initially at 2°C. The final temperature of the cooling water is 50°C. 
Assume (heat capacity of gluconic acid is 0.35 cal g-1 °C-1).
h (liquid water at 90°C = 376.9 kJ kg-1)
h (liquid water at 6°C = 25.2 kJ kg-1)
h (liquid water at 2°C = 8.4 kJ kg-1 )
h (liquid water at 50°C = 209.3 kJ kg-1)
h (gluconic acid at 90°C=0)
How much heat is removed to the cooling water?
TLS Online TPP Program

#Question id: 15469

#SCPH05 I Biotechnology

What is the rate of heat loss from the gluconic acid solution to the surroundings? 
TLS Online TPP Program

#Question id: 15470

#SCPH05 I Biotechnology

In the stoichiometric equation given below identify which one of the following corresponds to oxygen balance:
CwHxOyNz + aO2 + bHgOhNi cCHαOβNδ + dCO2 + eH2O